Zinc Chloride Anhydrous (ZnCl₂)
Zinc Chloride Anhydrous is a white, highly water-soluble inorganic compound. It is widely used as a Lewis acid catalyst in organic synthesis and various industrial applications.
1. Key Physical & Chemical Properties
- Basic Information:
- CAS Number: 7646-85-7
- Molecular Weight: 136.3 g/mol
- Appearance: White crystalline solid or AnhydroBeads™.
- Physical Data:
- Melting Point: Approx. 290°C - 318°C (varies by crystal form)
- Boiling Point: 732°C
- Density: 2.91 g/cm³
- Solubility: Very soluble in water (exothermic), alcohol, glycerol, and acetone.
- Chemical Characteristics:
- Hygroscopic: Highly deliquescent (absorbs moisture from air and may become liquid).
- Acidity: Aqueous solutions are strongly acidic due to hydrolysis.
2. Major Applications
-Organic Synthesis Catalyst: A common Lewis acid used in Friedel-Crafts acylation, indole cyclization, and as a condensing agent.
- Industrial Uses:
- Wood preservative
- Soldering flux (dissolves metal oxides)
- Sizing agent and mordant in textile processing
- Batteries & Metallurgy: Used in battery electrolytes and metal surface treatment.
3. Safety & Hazards (GHS Classification)
- Primary Hazards:
- Corrosive: Causes severe skin burns and eye damage.
- Aquatic Toxicity: Very toxic to aquatic life with long-lasting effects.
- Acute Toxicity: Harmful if swallowed.
- Hazard Statements: H314 (Causes severe skin burns and eye damage), H411 (Toxic to aquatic life with long-lasting effects).
- Precautionary Measures:
- Handling: Use in a fume hood. Avoid dust formation. Wash thoroughly after handling.
- Storage: Keep tightly sealed in a dry place to prevent deliquescence.
- First Aid:
- Skin contact: Remove contaminated clothing and rinse with plenty of water for at least 15 minutes.
- Inhalation: Move to fresh air. Seek medical attention if discomfort persists.
4. Available Purity Grades
-Reagent Grade (≥98%): Suitable for general laboratory synthesis and industrial use.
-High Purity Grade (99.99%+): Used in materials science (e.g., synthesis of zinc oxide thin films) and electronics.
Summary
Anhydrous Zinc Chloride,CAS Number: 7646-85-7 is a fundamental industrial chemical. Due to its strong hygroscopicity and acidity, proper protective equipment is essential during handling, and it must be stored in airtight, dry conditions.
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